Analytical methods

ExperimentID EXA000147
ChemicalID CH0001175
Chemical Name Pentachloroanisole
Official Method No
Chromatography GC
Chromatography mfr. 6890, Agilent / 7683, Agilent
Column DB-5ms 30 m x 0.25 mm, 0.25 μm
Column mfr. Agilent
Detector HRMS
Detector mfr. AutoSpec Ultima, Waters; AutoSpec Premier, Waters
Ionization SIM-EI
Extraction LLE
Extraction Details Extracted with Dichloromethane
Clean-up 1st
Clean-up 1st Details
Clean-up 2nd Column cleanup
Clean-up 2nd Details 5% Water-impregnated Silica Gel, Dichloromethane
Clean-up Spike 13C12-Pentachloroanisole
Syringe Spike 13C12-PCB#70
Derivatization BSTFA
Recovery Correction
Instrument Detection Limit
Instrument Quantification Limit
Method Detection Limit 6 pg/L
Method Quantification Limit 16 pg/L
Repeatability
Standard
Recovery (CRM)
Recovery (spiked)
Recovery (IS)
Protocol https://www.env.go.jp/chemi/kurohon/2019/shosai/3_7.pdf
Remarks Analysis method: p.450; Resolution: 10,000
RegisterDate 2021/5/21
UpdateDate 2021/5/21