ExperimentID |
EXA000161 |
ChemicalID |
CH0000057
|
Chemical Name |
PCB114 |
Official Method |
No |
Chromatography |
GC |
Chromatography mfr. |
6890, Agilent; 7683, Agilent |
Column |
HT8-PCB 60 m x 0.25 mm |
Column mfr. |
GL Sciences |
Detector |
HRMS |
Detector mfr. |
AutoSpec Ultima, Waters; AutoSpec Premier, Waters |
Ionization |
SIM-EI |
Extraction |
Solvent Extraction |
Extraction Details |
Ultrasonic extraction: Extracted with Acetone. After filtration, wash the residue in Acetone.; Soxhlet Extraction: Extracted with Toluene. |
Clean-up 1st |
Sulfate treatment |
Clean-up 1st Details |
Sulfate |
Clean-up 2nd |
Multilayer column cleanup; GPC |
Clean-up 2nd Details |
Multilayer column cleanup: Silica Gel, Copper powder, Silica Gel Sulfate, Anhydrous sodium sulfate; Washed/Eluted with Dichloromethane/Hexane (20:80); Gel permeation chromatography: Acetone/Cyclohexane (20:80), Precolumn: Shodex EV-G AC; Column: Shodex EV-2000 AC |
Clean-up Spike |
13C12-PCB#3, #8, #11, #28, #31, #52, #77, #81, #101, #105, #114, #118, #123, #126, #138, #153, #156, #157, #167, #169, #170, #180, #189, #206 or #209 |
Syringe Spike |
13C12-PCB#9, #19, #70, #111, #155, #178 or #202 |
Derivatization |
|
Recovery Correction |
|
Instrument Detection Limit |
|
Instrument Quantification Limit |
|
Method Detection Limit |
0.8 pg/g dry |
Method Quantification Limit |
2.4 pg/g dry |
Repeatability |
|
Standard |
|
Recovery (CRM) |
|
Recovery (spiked) |
|
Recovery (IS) |
|
Protocol |
https://www.env.go.jp/chemi/kurohon/2019/shosai/3_7.pdf |
Remarks |
Analysis method: p.438; Resolution: 10,000 |
RegisterDate |
2021/5/24 |
UpdateDate |
2021/5/24 |