| ExperimentID |
EXA000182 |
| ChemicalID |
CH0000502
|
| Chemical Name |
Toxaphene 50 |
| Official Method |
No |
| Chromatography |
GC |
| Chromatography mfr. |
7200 Q-TOF, Agilent |
| Column |
DB-35ms 30 m x 0.25 mm |
| Column mfr. |
Agilent |
| Detector |
TOF-MS |
| Detector mfr. |
7200 Q-TOF, Agilent |
| Ionization |
NICI |
| Extraction |
Solvent Extraction |
| Extraction Details |
Ultrasonic extraction: Extracted with Acetone. After filtration, wash the residue in Acetone.; Soxhlet Extraction: Extracted with Toluene. |
| Clean-up 1st |
Sulfate treatment |
| Clean-up 1st Details |
Sulfate |
| Clean-up 2nd |
Multilayer column cleanup; GPC |
| Clean-up 2nd Details |
Multilayer column cleanup: Silica Gel, Copper powder, Silica Gel Sulfate, Anhydrous sodium sulfate; Washed/Eluted with Dichloromethane/Hexane (20:80); Gel permeation chromatography: Acetone/Cyclohexane (20:80), Precolumn: Shodex EV-G AC; Column: Shodex EV-2000 AC |
| Clean-up Spike |
13C12-PCB#3, #8, #11, #28, #31, #52, #77, #81, #101, #105, #114, #118, #123, #126, #138, #153, #156, #157, #167, #169, #170, #180, #189, #206 or #209 |
| Syringe Spike |
13C12-PCB#9, #19, #70, #111, #155, #178 or #202 |
| Derivatization |
|
| Recovery Correction |
|
| Instrument Detection Limit |
|
| Instrument Quantification Limit |
|
| Method Detection Limit |
3 pg/g dry |
| Method Quantification Limit |
8 pg/g dry |
| Repeatability |
|
| Standard |
|
| Recovery (CRM) |
|
| Recovery (spiked) |
|
| Recovery (IS) |
|
| Protocol |
https://www.env.go.jp/chemi/kurohon/2019/shosai/3_7.pdf |
| Remarks |
Analysis method: p.438; Resolution: 13,000 |
| RegisterDate |
2021/5/24 |
| UpdateDate |
2021/5/24 |
