| ExperimentID |
EXA000211 |
| ChemicalID |
CH0000215
|
| Chemical Name |
PCP |
| Official Method |
No |
| Chromatography |
GC |
| Chromatography mfr. |
6890, Agilent; 7683, Agilent |
| Column |
DB-5ms 30 m x 0.25 mm, 0.25 μm |
| Column mfr. |
Agilent |
| Detector |
HRMS |
| Detector mfr. |
AutoSpec Ultima, Waters; AutoSpec Premier, Waters |
| Ionization |
SIM-EI |
| Extraction |
Solvent Extraction |
| Extraction Details |
Shaking extraction; Ultrasonic extraction: Extracted with Acetone |
| Clean-up 1st |
Washing |
| Clean-up 1st Details |
Washed in 5% Sodium chloride aqueous solution |
| Clean-up 2nd |
Column cleanup; Multilayer silica gel column cleanup |
| Clean-up 2nd Details |
Column cleanup: 5% Hidrous silica gel, Hexan (First fraction) and Dichloromethane (Second fraction); Only second fraction was ethylated.; Multilayer silica gel column cleanup: Silica gel sulfate, Silica gel, Silver nitrate silica gel, Anhydrous sodium sulfate; Washed in Hexan. Eluted with Hexane |
| Clean-up Spike |
13C12-Pentachlorophenol |
| Syringe Spike |
13C12-PCB 70 |
| Derivatization |
Ethylation |
| Recovery Correction |
|
| Instrument Detection Limit |
|
| Instrument Quantification Limit |
|
| Method Detection Limit |
6 pg/g dry |
| Method Quantification Limit |
18 pg/g dry |
| Repeatability |
|
| Standard |
|
| Recovery (CRM) |
|
| Recovery (spiked) |
|
| Recovery (IS) |
|
| Protocol |
https://www.env.go.jp/chemi/kurohon/2019/shosai/3_7.pdf |
| Remarks |
Analysis method: p.451; Resolution: 10,000 |
| RegisterDate |
2021/5/24 |
| UpdateDate |
2021/5/24 |
