| ExperimentID |
EXA000370 |
| ChemicalID |
CH0000827
|
| Chemical Name |
Σhexa-BDEs |
| Official Method |
No |
| Chromatography |
GC |
| Chromatography mfr. |
6890, Agilent; 7683, Agilent |
| Column |
HT8-PCB 60 m x 0.25 mm |
| Column mfr. |
GL Sciences |
| Detector |
HRMS |
| Detector mfr. |
AutoSpec Ultima, Waters; AutoSpec Premier, Waters |
| Ionization |
SIM-EI |
| Extraction |
SPE |
| Extraction Details |
Sequentially extracted with glass fiber filter GC50 and with SPE disk C18FF; Ultrasonic extraction with Acetone; |
| Clean-up 1st |
Multilayer column cleanup; GPC |
| Clean-up 1st Details |
Multilayer column cleanup: Silica Gel, Silica Gel Sulfate(50:50), Anhydrous sodium sulfate; Eluted with Hexane (First fraction), Dichloromethane/Hexane (20:80) (Second fraction) |
| Clean-up 2nd |
Column cleanup |
| Clean-up 2nd Details |
Florisil; Eluted with Dichloromethane/Hexane (20:80) |
| Clean-up Spike |
13C12-PBDE#3, #15, #28, #47, #99, #126, #153, #154, #183, #197, #207 or #209 |
| Syringe Spike |
PBDE#138; PBDE#206 |
| Derivatization |
|
| Recovery Correction |
|
| Instrument Detection Limit |
|
| Instrument Quantification Limit |
|
| Method Detection Limit |
1 pg/L |
| Method Quantification Limit |
2 pg/L |
| Repeatability |
|
| Standard |
|
| Recovery (CRM) |
|
| Recovery (spiked) |
|
| Recovery (IS) |
|
| Protocol |
https://www.env.go.jp/chemi/kurohon/2020/shosai/5_3_2.pdf |
| Remarks |
Analysis method: p.1; Resolution: 10,000 |
| RegisterDate |
2022/6/02 |
| UpdateDate |
2022/6/02 |
