| ExperimentID |
EXA000464 |
| ChemicalID |
CH0000102
|
| Chemical Name |
BDE66 |
| Official Method |
No |
| Chromatography |
GC |
| Chromatography mfr. |
7890 series, Agilent |
| Column |
Rtx-1614 column (15 m x 0.25 mm x 0.1 μm |
| Column mfr. |
Restek |
| Detector |
MS/MS |
| Detector mfr. |
7000 GC/MS Triple Quad, Agilent |
| Ionization |
|
| Extraction |
ASE |
| Extraction Details |
Extracted with a mixture of Hexane and acetone (1:1, v/v) using a SE-100 High-Speed Solvent Extractor (Mitsubishi Chemical Analytech, Japan), running at 35 ℃, at 6 mL/min for 30 min. |
| Clean-up 1st |
Chromatography; SPE |
| Clean-up 1st Details |
3 steps: [1] Gel-permeation chromatography; [2] SPE step using Supelclean TM sulfoxide cartoridge (3 g/6 mL, Sigma-Aldrich) conditioned with 20 mL hexane in order to remove vehicle oil-related matrices in the VP samples cartridge; [3] Activated silica chromatography; Eluted with 40 mL acetone/hexane mixture (1:9, v/v) |
| Clean-up 2nd |
Wash |
| Clean-up 2nd Details |
Washed with 5 mL hexane |
| Clean-up Spike |
13C12-BDE#28, #47, #99, #100, #153, #154, #183, #197, #207, #209; 13C10-anti-DP |
| Syringe Spike |
|
| Derivatization |
|
| Recovery Correction |
|
| Instrument Detection Limit |
|
| Instrument Quantification Limit |
|
| Method Detection Limit |
2.0-2.6 ng/g dry |
| Method Quantification Limit |
|
| Repeatability |
|
| Standard |
|
| Recovery (CRM) |
|
| Recovery (spiked) |
|
| Recovery (IS) |
|
| Protocol |
|
| Remarks |
|
| RegisterDate |
2022/8/08 |
| UpdateDate |
2022/8/08 |
