Analytical methods

ExperimentID EXA000552
ChemicalID CH0000824
Chemical Name ΣPBDEs (Br4-Br10)
Official Method No
Chromatography GC
Chromatography mfr. HP6890GC, Agilent
Column BP1 15 m x 0.25 mm, 0.10 μm
Column mfr. SGE
Detector HRMS
Detector mfr. AutoSpec Premier, Waters
Ionization SIM-EI
Extraction Soxhlet Extraction
Extraction Details Air collection: QFF, PUF and ACF; Extracted with Acetone and Toluene (QFF, ACF), with Acetone (PUF)
Clean-up 1st Column cleanup
Clean-up 1st Details Column cleanup: Supelclean Sulfoxide 6 g; Remove interfering substance with Hexane; Eluted with Acetone
Clean-up 2nd Multilayer column cleanup
Clean-up 2nd Details Silica gel, Sulfuric acid/Silica gel (22:78), Sulfuric acid/Silica gel (44:56), Silica gel, Potassium hydroxide/Slica gel (2:98), Silica gel; Eluted with Hexane (First fraction), Dichloromethane/Hexane (50:50)(Second fraction)
Clean-up Spike 13C12-PBDE#47, #99, #153, #154, #183, #204, #207, #209
Syringe Spike 13C12-PBDE#138
Derivatization
Recovery Correction
Instrument Detection Limit
Instrument Quantification Limit
Method Detection Limit 0.5 pg/m3
Method Quantification Limit 1.5 pg/m3
Repeatability
Standard
Recovery (CRM)
Recovery (spiked)
Recovery (IS)
Protocol https://www.env.go.jp/chemi/kurohon/2020/shosai/5_3_2.pdf
Remarks Analysis method: p.6; Resolution: 10,000
RegisterDate 2022/9/27
UpdateDate 2022/9/27