| ExperimentID |
EXA000587 |
| ChemicalID |
CH0001520
|
| Chemical Name |
Dicofol |
| Official Method |
No |
| Chromatography |
GC |
| Chromatography mfr. |
HP6890GC, Agilent |
| Column |
DB-5ms 15 m x 0.25 mm, 0.25 μm |
| Column mfr. |
Agilent |
| Detector |
HRMS |
| Detector mfr. |
AutoSpec Premier, Waters |
| Ionization |
SIM-EI |
| Extraction |
Soxhlet Extraction |
| Extraction Details |
Air collection: QFF, PUF and ACF; Extracted with Acetone and Toluene (QFF, ACF), with Acetone (PUF) |
| Clean-up 1st |
Column cleanup |
| Clean-up 1st Details |
Column cleanup: Supelclean Sulfoxide 3 g; Remove interfering substance with Hexane; Eluted with Hexane (First fraction), Acetone (Second fraction) |
| Clean-up 2nd |
Column cleanup |
| Clean-up 2nd Details |
Florisil; Eluted with Dichloromethane/Hexane (20:80) |
| Clean-up Spike |
13C12-p.p'-DDT |
| Syringe Spike |
13C12-PCB#70 |
| Derivatization |
|
| Recovery Correction |
|
| Instrument Detection Limit |
|
| Instrument Quantification Limit |
|
| Method Detection Limit |
0.2 pg/m3 |
| Method Quantification Limit |
0.4 pg/m3 |
| Repeatability |
|
| Standard |
|
| Recovery (CRM) |
|
| Recovery (spiked) |
|
| Recovery (IS) |
|
| Protocol |
https://www.env.go.jp/chemi/kurohon/2020/shosai/5_3_2.pdf |
| Remarks |
Analysis method: p.8; Resolution: 10,000 |
| RegisterDate |
2022/9/27 |
| UpdateDate |
2022/9/27 |
